SEM micrograph of lithium pancake deposits

Georgia Institute of Technology

Oyakhire Lab

Grand challenges in energy storage, environmental stewardship, and environmental remediation require innovations in coupled ion-electron transfer at electrified interfaces.

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4

Research Areas

2025

Lab Founded

Research Summary

The Oyakhire Lab studies and controls ion and electron transfer at solid-liquid interfaces in electrochemical systems. These interfacial charge-transfer processes determine the macroscopic performance of batteries, electrocatalytic cells, and related technologies. Using insights from charge transfer measurements, we design next-generation energy storage and conversion devices.

We follow an iterative investigative cycle

1. Synthesize

Hypothesis-informed materials such as thin films and small molecules using tunable methods.

2. Probe

Ion- and electron-transfer mechanisms to determine how these materials influence device properties such as efficiency.

3. Refine

Material design recursively using the resulting mechanistic insights to optimize performance.

Group News

01/13/2026

Luke and Gene pass their PhD qualifying exams. Congratulations!!

12/01/2025

The lab receives a Schmidt Science Fellows Catalyst Grant!

10/01/2025

Dr. Oyakhire is thrilled to welcome his first set of PhD students, Gene Koifman and Luke Cravey.

08/01/2025

Dr. Oyakhire starts the lab at Georgia Tech.

Research Areas

We study and control charge transfer at solid-liquid interfaces to advance batteries, electrocatalysis, and electrochemical separations.

SEM micrograph of lithium pancake deposits on a substrate

Electrodeposition in high-energy-density batteries

During charging, lithium- and sodium-metal batteries undergo electrically driven metal deposition and growth. Despite the central role of electrodeposition in battery performance and safety, it remains poorly understood. Using well-defined thin-film substrates, we elucidate key steps in metal growth within batteries, with the goal of enabling long-lasting, stable batteries.

Schematic of selective electrochemical metal recovery from non-aqueous electrolyte

Electrochemical resource recovery

Recycling minerals from waste is essential for environmental stewardship and equitable resource distribution. Conventional approaches such as chemical leaching, hydrometallurgy, and pyrometallurgy are limited in selectivity and efficiency. We exploit precise control over electron transfer and the tunability of electrochemical free energy to recover valuable resources from complex waste mixtures.

XPS F 1s spectrum showing LiF and lithium oxyfluorophosphate SEI components

Tracking the evolution of electrically active interphases

The electric double layer (EDL), the solid electrolyte interphase (SEI), and the cathode–electrolyte interphase (CEI) mediate dynamic charge-transfer processes in batteries and electrocatalytic devices. Yet these inter(phases)faces have historically been measured using ex-situ, post-mortem techniques. We develop operando spectroscopy and acoustic sensing methods to provide real-time insights into inter(phase)face evolution, and guide the design of passivation layers that enhance battery cycle life.

Hypothesis-Informed Physics-coupled AI framework for electrolyte design

Small-molecule discovery and design for electrochemical devices

In liquid cells, ion transport and electrode passivation are governed by the properties of small molecules. The vast design space of small molecules necessitates artificial-intelligence tools to identify optimal electrolytes. We develop Hypothesis-Informed, Physics-coupled Artificial Intelligence (HIP-AI) to design new molecules for batteries and resource-recovery cells. HIP-AI enables (i) discovery of new molecules through filtering and generative capabilities; (ii) interpretability via physics-coupled algorithms; and (iii) experimentally actionable outputs by linking experimental design parameters to HIP-AI features.

Publications

* denotes co-first authors · = first / co-first author

  1. 34. Cryogenic X-ray photoelectron spectroscopy for battery interfaces
    Sanzeeda Baig Shuchi, Giulio D'Acunto, Philaphon Sayavong, Solomon T Oyakhire, Kenzie M Sanroman Gutierrez, Juliet Risner-Jamtgaard, Il Rok Choi, Yi Cui, Stacey F Bent
    Nature 646 (8086), 850–855 (2025)
  2. 33. Elucidating the Effects of LiF on Lithium Metal Anodes
    Mun Sek Kim, Jingyang Wang, Wenbo Zhang, Philaphon Sayavong, Zewen Zhang, Solomon T Oyakhire, Sanzeeda Baig Shuchi, Sang Cheol Kim, Yi Cui, Yuelang Chen, Zhiao Yu, Huaxin Gong, Rong Xu, Junyoung Lee, Il Rok Choi, Jun Ho Lee, Kristin A Persson, Jian Qin, Zhenan Bao, Yi Cui
    Nano Letters 25 (40), 14625–14634 (2025)
  3. 32. Galvanic Corrosion Underlies Coulombic Efficiency Differences in High-Performing Lithium Metal Battery Electrolytes
    Solomon T Oyakhire*, Sang Cheol Kim*, Wenbo Zhang*, Sanzeeda Baig Shuchi*, Yi Cui, Stacey F Bent
    Energy & Environmental Science 18, 4847–4858 (2025)
  4. 31. Equal resistance single and bilayer films decouple role of solid electrolyte interphase from lithium morphology in batteries
    Sanzeeda Baig Shuchi, Kenzie M Sanroman Gutierrez, Alexander B Shearer, Solomon T Oyakhire, Yi Cui, Stacey F Bent
    EES Batteries 1, 585 (2025)
  5. 30. Mitigating Battery Cell Failure: Role of Ag‑Nanoparticle Fillers in Solid Electrolyte Dendrite Suppression
    Mouhamadou S Diallo, Tofunmi Ogunfunmi, Xiaochen Yang, Solomon Tolulope Oyakhire, Venkata Sai Avvaru, Mary Cooper Scott, Qingsong Howard Tu, Gerbrand Ceder
    Advanced Energy Materials, 2405700 (2025)
  1. 29. Recovery of isolated lithium through discharged state calendar ageing
    Wenbo Zhang, Philaphon Sayavong, Xin Xiao, Solomon T Oyakhire, Sanzeeda Baig Shuchi, Rafael A Vilá, David T Boyle, Sang Cheol Kim, Mun Sek Kim, Sarah E Holmes, Yusheng Ye, Donglin Li, Stacey F Bent, Yi Cui
    Nature 626 (7998), 306–312 (2024)
  2. 28. Quadruple the rate capability of high-energy batteries through a porous current collector design
    Yusheng Ye, Rong Xu, Wenxiao Huang, Huayue Ai, Wenbo Zhang, Jordan Otto Affeld, Andy Cui, Fang Liu, Xin Gao, Zhouyi Chen, Tony Li, Xin Xiao, Zewen Zhang, Yucan Peng, Rafael A Vila, Yecun Wu, Solomon T Oyakhire, Hideaki Kuwajima, Yoshiaki Suzuki, Ryuhei Matsumoto, Yasuyuki Masuda, Takahiro Yuuki, Yuri Nakayama, Yi Cui
    Nature Energy, 1–11 (2024)
  3. 27. Deconvoluting Effects of Lithium Morphology and SEI Stability at Moderate Current Density Using Interface Engineering
    Sanzeeda Baig Shuchi*, Solomon T Oyakhire*, Wenbo Zhang, Philaphon Sayavong, Yusheng Ye, Yuelang Chen, Zhiao Yu, Yi Cui, Stacey F Bent
    Advanced Materials Interfaces 11 (36), 2400693 (2024) Featured on journal cover
  4. 26. Interfacial Engineering of Lithium Metal Anodes: What is Left to Uncover?
    Solomon T Oyakhire, Stacey F Bent
    Energy Advances 3, 108–120 (2024)
  1. 25. Correlating the formation protocols of solid electrolyte interphases with practical performance metrics in lithium metal batteries
    Solomon T Oyakhire, Wenbo Zhang, Zhiao Yu, Sarah E Holmes, Philaphon Sayavong, Sang Cheol Kim, David T Boyle, Mun Sek Kim, Zewen Zhang, Yi Cui, Stacey F Bent
    ACS Energy Letters 8 (1), 869–877 (2023)
  2. 24. Revealing the Multifunctions of Li₃N in the Suspension Electrolyte for Lithium Metal Batteries
    Mun Sek Kim, Zewen Zhang, Jingyang Wang, Solomon T Oyakhire, Sang Cheol Kim, Zhiao Yu, Yuelang Chen, David T Boyle, Yusheng Ye, Zhuojun Huang, Wenbo Zhang, Rong Xu, Philaphon Sayavong, Stacey F Bent, Jian Qin, Zhenan Bao, Yi Cui
    ACS Nano 17 (3), 3168–3180 (2023)
  3. 23. Data-driven electrolyte design for lithium metal anodes
    Sang Cheol Kim*, Solomon T Oyakhire*, Constantine Athanitis, Jingyang Wang, Zewen Zhang, Wenbo Zhang, David T Boyle, Mun Sek Kim, Zhiao Yu, Xin Gao, Tomi Sogade, Esther Wu, Jian Qin, Zhenan Bao, Stacey F Bent, Yi Cui
    Proceedings of the National Academy of Sciences 120 (10), e2214357120 (2023)
  4. 22. Molecular Layer Deposition of Organic–Inorganic Hafnium Oxynitride Hybrid Films for Electrochemical Applications
    Hayrensa Ablat, Il-Kwon Oh, Nathaniel E Richey, Solomon T Oyakhire, Yufei Yang, Wenbo Zhang, William Huang, Yi Cui, Stacey F Bent
    ACS Applied Energy Materials 6 (11), 5806–5816 (2023)
  5. 21. Dissolution of the solid electrolyte interphase and its effects on lithium metal anode cyclability
    Philaphon Sayavong, Wenbo Zhang, Solomon T Oyakhire, David T Boyle, Yuelang Chen, Sang Cheol Kim, Rafael A Vilá, Sarah E Holmes, Mun Sek Kim, Stacey F Bent, Zhenan Bao, Yi Cui
    Journal of the American Chemical Society 145 (22), 12342–12350 (2023)
  6. 20. Autonomous alignment and healing in multilayer soft electronics using immiscible dynamic polymers
    Christopher B Cooper, Samuel E Root, Lukas Michalek, Shuai Wu, Jian-Cheng Lai, Muhammad Khatib, Solomon T Oyakhire, Renee Zhao, Jian Qin, Zhenan Bao
    Science 380 (6648), 935–941 (2023)
  7. 19. High-entropy electrolytes for practical lithium metal batteries
    Sang Cheol Kim, Jingyang Wang, Rong Xu, Pu Zhang, Yuelang Chen, Zhuojun Huang, Yufei Yang, Zhiao Yu, Solomon T Oyakhire, Wenbo Zhang, Louisa C Greenburg, Mun Sek Kim, David T Boyle, Philaphon Sayavong, Yusheng Ye, Jian Qin, Zhenan Bao, Yi Cui
    Nature Energy 8 (8), 814–826 (2023)
  8. 18. Ultrahigh‑Loading Manganese‑Based Electrodes for Aqueous Batteries via Polymorph Tuning
    Xin Xiao, Zewen Zhang, Yecun Wu, Jinwei Xu, Xin Gao, Rong Xu, Wenxiao Huang, Yusheng Ye, Solomon T Oyakhire, Pu Zhang, Baoliang Chen, Emre Cevik, Sarah M Asiri, Ayhan Bozkurt, Khalil Amine, Yi Cui
    Advanced Materials 35 (33), 2211555 (2023)
  9. 17. Proximity matters: interfacial solvation dictates solid electrolyte interphase composition
    Solomon T Oyakhire, Sheng-Lun Liao, Sanzeeda Baig Shuchi, Mun Sek Kim, Sang Cheol Kim, Zhiao Yu, Rafael A Vilá, Paul E Rudnicki, Yi Cui, Stacey F Bent
    Nano Letters 23 (16), 7524–7531 (2023)
  10. 16. Interphase formation on Al₂O₃-coated carbon negative electrodes in lithium-ion batteries
    R Vilá*, S Oyakhire*, Y Cui
    ChemRxiv (2023)
  1. 15. Rational solvent molecule tuning for high-performance lithium metal battery electrolytes
    Zhiao Yu, Paul E Rudnicki, Zewen Zhang, Zhuojun Huang, Hasan Celik, Solomon T Oyakhire, Yuelang Chen, Xian Kong, Sang Cheol Kim, Xin Xiao, Hansen Wang, Yu Zheng, Gaurav A Kamat, Mun Sek Kim, Stacey F Bent, Jian Qin, Yi Cui, Zhenan Bao
    Nature Energy 7 (1), 94–106 (2022)
  2. 14. Scalable, Ultrathin, and High‑Temperature‑Resistant Solid Polymer Electrolytes for Energy‑Dense Lithium Metal Batteries
    Yinxing Ma, Jiayu Wan, Yufei Yang, Yusheng Ye, Xin Xiao, David T Boyle, Will Burke, Zhuojun Huang, Hao Chen, Yi Cui, Zhiao Yu, Solomon T Oyakhire, Yi Cui
    Advanced Energy Materials, 2103720 (2022)
  3. 13. Capturing the swelling of solid-electrolyte interphase in lithium metal batteries
    Zewen Zhang, Yuzhang Li, Rong Xu, Weijiang Zhou, Yanbin Li, Solomon T Oyakhire, Yecun Wu, Jinwei Xu, Hansen Wang, Zhiao Yu, David T Boyle, William Huang, Yusheng Ye, Hao Chen, Jiayu Wan, Zhenan Bao, Wah Chiu, Yi Cui
    Science 375 (6576), 66–70 (2022)
  4. 12. Graphene coating on silicon anodes enabled by thermal surface modification for high-energy lithium-ion batteries
    Sang Cheol Kim, William Huang, Zewen Zhang, Jiangyan Wang, Yongseok Kim, You Kyeong Jeong, Solomon T Oyakhire, Yufei Yang, Yi Cui
    MRS Bulletin 47 (2), 127–133 (2022)
  5. 11. Methyl-methacrylate based aluminum hybrid film grown via three-precursor molecular layer deposition
    Solomon T Oyakhire*, Hayrensa Ablat*, Nathaniel E Richey, Stacey F Bent
    Journal of Vacuum Science & Technology A 40 (2) (2022) Editor's choice
  6. 10. Suspension electrolyte with modified Li⁺ solvation environment for lithium metal batteries
    Mun Sek Kim, Zewen Zhang, Paul E Rudnicki, Zhiao Yu, Jingyang Wang, Hansen Wang, Solomon T Oyakhire, Yuelang Chen, Sang Cheol Kim, Wenbo Zhang, David T Boyle, Xian Kong, Rong Xu, Zhuojun Huang, William Huang, Stacey F Bent, Lin-Wang Wang, Jian Qin, Zhenan Bao, Yi Cui
    Nature Materials 21 (4), 445–454 (2022)
  7. 9. Understanding and utilizing reactive oxygen reservoirs in atomic layer deposition of metal oxides with ozone
    Joel R Schneider, Camila de Paula, Nathaniel E Richey, Jon G Baker, Solomon T Oyakhire, Stacey F Bent
    Chemistry of Materials 34 (12), 5584–5597 (2022)
  8. 8. A Solution‑Processable High‑Modulus Crystalline Artificial Solid Electrolyte Interphase for Practical Lithium Metal Batteries
    Zhiao Yu, Samuel Seo, Jongchan Song, Zewen Zhang, Solomon T Oyakhire, Yang Wang, Rong Xu, Huaxin Gong, Song Zhang, Yu Zheng, Yuchi Tsao, Luca Mondonico, Eder G Lomeli, Xinchang Wang, Wonkeun Kim, Kyounghan Ryu, Zhenan Bao
    Advanced Energy Materials, 2201025 (2022)
  9. 7. Electrical resistance of the current collector controls lithium morphology
    Solomon T Oyakhire*, Wenbo Zhang*, Andrew Shin, Rong Xu, David T Boyle, Zhiao Yu, Yusheng Ye, Yufei Yang, James A Raiford, William Huang, Joel R Schneider, Yi Cui, Stacey F Bent
    Nature Communications 13 (1), 3986 (2022)
  10. 6. An X-ray photoelectron spectroscopy primer for solid electrolyte interphase characterization in lithium metal anodes
    Solomon T Oyakhire*, Huaxin Gong*, Yi Cui, Zhenan Bao, Stacey F Bent
    ACS Energy Letters 7 (8), 2540–2546 (2022)
  11. 5. An Interdigitated Li‑Solid Polymer Electrolyte Framework for Interfacial Stable All‑Solid‑State Batteries
    Yufei Yang, Hao Chen, Jiayu Wan, Rong Xu, Pu Zhang, Wenbo Zhang, Solomon T Oyakhire, Sang Cheol Kim, David T Boyle, Yucan Peng, Yinxing Ma, Yi Cui
    Advanced Energy Materials, 2201160 (2022)
  12. 4. Correlating kinetics to cyclability reveals thermodynamic origin of lithium anode morphology in liquid electrolytes
    David T Boyle, Sang Cheol Kim, Solomon T Oyakhire, Rafael A Vilá, Zhuojun Huang, Philaphon Sayavong, Jian Qin, Zhenan Bao, Yi Cui
    Journal of the American Chemical Society 144 (45), 20717–20725 (2022)
  13. 3. Investigating the cyclability and stability at the interfaces of composite solid electrolytes in Li metal batteries
    Sarah E Holmes, Fang Liu, Wenbo Zhang, Philaphon Sayavong, Solomon T Oyakhire, Yi Cui
    ACS Applied Materials & Interfaces 14 (48), 53736–53743 (2022)
  1. 2. Applications of atomic layer deposition and chemical vapor deposition for perovskite solar cells
    James A Raiford, Solomon T Oyakhire, Stacey F Bent
    Energy & Environmental Science 13 (7), 1997–2023 (2020)
  2. 1. Revealing and elucidating ALD‑derived control of lithium plating microstructure
    Solomon T Oyakhire*, William Huang*, Hansen Wang, David T Boyle, Joel R Schneider, Camila de Paula, Yecun Wu, Yi Cui, Stacey F Bent
    Advanced Energy Materials 10 (44), 2002736 (2020)

Meet the Team

Prof. Solomon Oyakhire

Prof. Solomon Oyakhire

Principal Investigator

Solomon Oyakhire is an Assistant Professor of Chemical and Biomolecular Engineering at Georgia Tech. He earned his BSc in Chemical Engineering from the University of Lagos, Nigeria, graduating with the highest honors and recognized as the department's best graduating student.

He completed his PhD in Chemical Engineering at Stanford University working on interfacial electrochemistry with Stacey Bent and Yi Cui as a Knight-Hennessy scholar. During his postdoctoral training at the University of California Berkeley, he developed artificial intelligence algorithms for high dimensional datasets with Kristin Persson and Gerbrand Ceder as a Schmidt Science Fellow.

Graduate Students

Gene Koifman

Gene Koifman

PhD Student

Undergrad Institution

Florida Institute of Technology

Luke Cravey

Luke Cravey

PhD Student

Undergrad Institution

Auburn University

Join the Lab

We are actively recruiting PhD students and postdocs. Our group thrives on interdisciplinarity, so we welcome applicants from a wide range of scientific backgrounds.

Contact Us to Apply

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